Career
She was a daughter of Prince Georgy Gruzinsky and Varvara Nikolayevna Bakhmetev. Princess Ana was born on 31 January 1798 in Moscow. Princess Ana married Prince Alexander Petrovych Tolstoy (1801-1873) but had no children.
According to a lady-in-waiting of the Russian imperial house Aleksandra Osypovna Smirova:
She died in Moscow on 17 July 1889.