Porpaoin turned pro in 1988 and captured the World Boxing Association minimumweight title with a majority decision win over Hideyuki Ohashi in 1993. He recaptured the belt in 2001 with a win over Keitaro Hoshino, but lost the belt in his first defense to Yutaka Niida.
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He defended the title 8 times before losing it to Rosendo Alvarez in 1995 by split decision.