Background
Denisov, Evguenii Timofeevich was born on June 19, 1930 in Kaluga, Russia. Son of Timofey Arsentievich and Olga Nikolaevna (Barsheva) Denisov.
(This text explores nonbranching reactions, including in-d...)
This text explores nonbranching reactions, including in-depth information on the inhibitors of free radical polymerisation and the mechanisms of antioxidants on oxidationprocesses. Auto-initiated chain reactions are also explored, with detailed descriptions on the kinetics, mechanisms, and inhibition of the autoxidation of organic compounds, A special chapter deals with the synergism of antioxidant actions. The theory of chain-branching reactions is investigated, and a large amount of new experimental data concerning the use of chemical additives to regulate combustion processes is also presented, including the mode of chain thermal explosion.
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(Designed for scientists and engineers involved in the che...)
Designed for scientists and engineers involved in the chemistry and technology of antioxidants, the Second Edition of this popular handbook continues to provide comprehensive data on the thermodynamics and reactivity of antioxidants. Fully revised and updated, the Second Edition provides the latest data on antioxidants and polymer stabilizers, new data for biological antioxidants, a corrected list of bond dissociation energies, and a full bibliography. Additions and changes in the New Edition: • The latest data on O-H bond dissociation energies of phenols and the new scale these values • Thermodynamic functions of antioxidants and their intermediate presented in tables • A table with current data on dissociation energies of C-H bonds of hydrocarbons and oxygen-containing compounds • Rate constants and activation energies of reactions of antioxidants with ozone, nitrogen dioxide, and hydroperoxide • Kinetic characteristics of benzoquinine reactions with antioxidants • Rate constants of free radical generation through biomolecular reactions with ozone, nitrogen dioxide, and hydroperoxide • All calculated data from the first edition has been recalculated in accordance with new data on dissociation energies and parameters of reactivity • Data on thermodynamics of hydrogen bond formation of antioxidants • All data on cyclic mechanisms of chain termination by antioxidants collected into a special chapter • Special chapters on bioantioxidants and stabilization of polymers The Handbook of Antioxidants puts essential data at your fingertips. Its comprehensive nature and ease-of-use make it the resource for scientific researchers and engineers working in the field of physical chemistry of antioxidants.
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(Free radical initiators-chemical molecules which easily d...)
Free radical initiators-chemical molecules which easily decompose into free radicals-serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: * Dialkyl Peroxides and Hydroperoxides* Diacyl Peroxides, Peresters, and Organic Polyoxides* Azo-Compounds* Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules* Free Radical Abstraction Reactions* Free Radical Addition Reactions* Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
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(The past 25 years in chemical kinetics have seen major ad...)
The past 25 years in chemical kinetics have seen major advances in studyiqg the mechanisms of complex chemical re actions, in particular free radical reactions. Many differ ent methods have been developed for quantitative studies of elementary chemical reactions. Thousands of rate constants have been measured, for hundreds of diverse chemical reac tions. It is becoming more and more difficult for the chemist to orient himself in the voluminous and rapidly growing liter ature of chemical reaction kinetics. This leads to major expenditures of time in searching out, collecting. and eval uating quantitative kinetic data; to unnecessary repetition (duplication) of research; and to a situation in which the rich material already accumulated in the field of chemical kinetics is very often not fully utilized in comparing, interpreting, and analyzing new experimental data. There is a pressing need for the creation of a series of handbooks on reaction rate constants. Such work was begun several years ago at the initiative of V. N. Kondrat'ev, and is now going forward under his direction at the Institute of Chemical Physics of the USSR Academy of Sciences. This book is devoted to liquid-phase, homolytic reactions. Part One contains data on monomolecular reactions in which molecules decompose to form radicals, as well as data on bi molecular and trimolecular reactions that form free radicals.
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Denisov, Evguenii Timofeevich was born on June 19, 1930 in Kaluga, Russia. Son of Timofey Arsentievich and Olga Nikolaevna (Barsheva) Denisov.
Diploma, University Moscow, 1953. Doctor of Philosophy, University Moscow, 1957. Doctorate, Institute Chemical Physics, Moscow, 1966.
Junior researcher, Institute Chemical Physics, Chernogolovka, Russia, 1956-1960;
senior researcher, Institute Chemical Physics, Chernogolovka, Russia, 1960-1967;
head of laboratory, Institute Chemical Physics, Chernogolovka, Russia, since 1967. Member of commission International Union of Pure and Applied Chemistry, 1979-1987, chairman 1989-1991. Chairman of the section science county Academy Union of the Soviet Socialist Republics, 1972-1997.
Chairman science county Institute Chemical Physics, since 1977.
(Free radical initiators-chemical molecules which easily d...)
(Designed for scientists and engineers involved in the che...)
(This text explores nonbranching reactions, including in-d...)
(The past 25 years in chemical kinetics have seen major ad...)
Member Academy of Creative Endeavours, International Academy of Science.
Married Zoya Alexeevna Shmeleva, January 8, 1954 (divorced January 1980). Children: Oleg, Vladimir. Married Taissa Grigorievna Lupenko, February 9, 1980.