Career
Sambenedettese
Born in San Benedetto del Tronto, Marche, Piccioni started his career at hometown club Sambenedettese. Since 2007-2008 season he played for its under-20 team In 2008-2009 Lega Pro Prima Divisione he also played 4 games for the first team
Vicenza
In January 2009 he was sold to Serie B team Vicenza for €100,000 along with Mattia Evangelisti (€100,000), Filippo Forò (€150,000) and German Pomiro (€100,000).
Sambenedettese also signed Stefano Pietribiasi (€150,000) and Marco Zentil (€150,000) in exchange. The two clubs also retained 50% registration rights of the 6 players.
Piccioni signed a 2½ year contract. In June 2009 the co-ownership deal was renewed except Evangelisti (to Vicenza) and Zentil (to Sambenedettese).
However Sambenedettese soon bankrupted.
Piccioni played 18 games in under-20 league in 2009-2010 season. L"Aquila
In August 2010 he was sold to L"Aquila of Lega Pro Seconda Divisione (Italian fourth division). Piccioni only played a handful game for the first team but was selected by Lega Pro under-20 representative team once, for a training camp.
On 31 August 2011 Piccioni returned to LP Prima Divisione (Italian third division) for Lanciano.
On the same day L"Aquila signed Roberto Colussi in exchange.