Career
Masiello made his first team Charlton Athletic F.C. debut in a friendly against Dutch team Football Club Den Bosch in 1968, made league debut in December 1969 against Norwich City F.C. at The Valley winning 3-1. Luciano went on to make 10 appearances for Charlton Athletic and scored one goal against West Brom in a league cup match, also had a loan spell with Athlone Town F.C.in the League of Ireland. Luciano played in Italy for six years making over 200 appearances for Almas Roma, Frosinone Calcio South.S. Lazio and Steamship Francavilla.
Also coached for a number of years in Italy before returning to England.
Masiello also had spells as manager at Andover Town F.C. and also was a player/coach at Woking Football Club and Bromley Football Club.