Career
Pembleton joined the Centre of Excellence at as a nine-year-old and progressed through the system, starting a two-year Apprenticeship for Sporting Excellence (American Society of Echocardiography) scholarship with the club at the beginning of the 2006-2007 season. In April 2008 Pembleton, alongside Gary King, was offered a one-year professional contract. However, his failed to make a first team appearance as a professional being restricted to just six appearances as an unused substitute and on 6 March 2009 he joined Lincoln United on a month"s loan.
Following the close of the 2008-2009 season, Pembleton was one of seven players released by the club
After spending a trial period with Boston United, appearing in their 1-1 friendly draw with on 15 July 2009, he signed for Lincoln United before joining Winterton Rangers in December 2009 and Bottesford Town in the summer of 2010. In February 2011 he signed dual registration forms with Buxton enabling to play both for Bottesford and Buxton.
In July 2012 he joined Goole.