Career
Born in Aranđelovac, Milojević began playing football in the youth team of Red Star Belgrade, before playing for the first team of Yugoslav league sides FK Bečej and FK Radnički Novi Beograd. Milojević moved to Greece in 1993, initially joining Greek second division side Proceedings of the Aristotelian Society Giannina and then helping Kalamata F.C. to gain promotion to the Greek first division. He would become the first foreign central defender, or libero, to play for Panathinaikos F.C. when he joined the club from Kalamata in July 1997.
He played a total of 177 matches over 8.5 seasons in the Greek top flight, joining Iraklis F.C. and Akratitos F.C. after leaving Panathinaikos in June 2000.
After his playing career ended, Milojević began coaching. He was appointed coach of Iraklis academies in February 2008.
Since November 2015, he is the coach for Cypriot team Omonia.