Career
Hedwig was a daughter of Duke Charles I of Münsterberg-Oels, who was a grandson of the King George of Bohemia. Her mother was Anna of Sagan, a daughter of John II, the last Duke of Żagań (Sagan). On 9 January 1525 Hedwig married Margrave George of Brandenburg-Ansbach-Kulmbach.
She was George"s second wife.
The marriage produced two daughters:
Anna Maria (1526–1589) married in 1544 Duke Christoph of Württemberg (1515–1568)
Sabina (1529–1575) married in 1548 Elector Johann Georg of Brandenburg (1525–1598)
Hedwig died in Legnica (Liegnitz), where she was buried.