Career
Volpe joined Juventus along with Domenico Criscito in 2004 in co-ownership deal, for €1.9M (both priced €19M in full ownership, but sold back 50% to for €095M and €095M, and paid via the transfer of Antonio Nocerino in co-ownership deal, priced €450,000). Volpe signed a 5-year contract. They went through the Juventus youth system.
Volpe was bought permanently in June 2005 for another €250,000, as Genoa cut €700,000.
In 2006 he joined Ravenna Calcio, on loan from Juventus with option to sign 50% rights for €450,000, which Ravenna did in June. In July 2007 he joined Associate of Science Livorno Calcio of Serie A in another co-ownership deal.
Livorno paid Juve €1M and Juve paid the same amount to Ravenna to acquire him. In July 2009 he was loaned to Triestina, where he made 15 starts in 22 league appearances.
In June 2011 Juventus gave up the remain 50% registration rights to Livorno, made a write-down of €617,000.
On 31 August he was sold to Piacenza in another co-ownership deal. for €500, along with Fabrizio Di Bella on loan. They were part of the deals that Antonio Piccolo joined Livorno. During the season Piacenza bankrupted and a new entity "Lupa Piacenza" restarted in amateur level
In September 2012 Volpe signed a 1-year deal with Lupa Piacenza.
The club promoted to 2013-2014 Serie Doctorate and renamed to Piacenza Calcio 1919. Volpe also renewed his contract with the club