Career
Born in Rome, capital of Lazio region and Italy, Volpe started his career at South.S. Lazio. In July 2004 Volpe left for Serie B club Ternana. In 2005 he was signed by Olbia.
After a season in 2005-2006 Serie C2, Volpe was signed by Empoli F.C. but loaned back to Sardinia for 2006-2007 Serie C2.
In 2007 Olbia re-signed half of the registration rights, and bought outright in June 2008. Volpe left for Lanciano in mid-2008.
After half season in 2008-2009 Lega Pro Prima Divisione, Volpe returned to Olbia. On 31 August 2009 Volpe left for Monopoli.
On 14 August 2013 he moved to Lega Pro Prima Divisione club Salernitana.